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A while back, we asked the BuzzFeed Community which TV actors have the best chemistry. There were so many great responses, and a lot of them included actors who met for the first time on their shows. So, here are some of the best acting duos whose chemistry is so incredible, it's shocking they didn't know each other before:
1. Sandra Oh and Jodie Comer as Eve and Villanelle on Killing Eve.
2. Sam Heughan and Caitriona Balfe as Jamie and Claire on Outlander.
3. Phoebe Dynevor and Regé-Jean Page as Daphne and Simon on Bridgerton.
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4. Andy Samberg and Melissa Fumero as Jake and Amy on Brooklyn Nine-Nine.
5. Iain De Caestecker and Elizabeth Henstridge as Fitz and Simmons on Agents of S.H.I.E.L.D.
6. Hugh Dancy and Mads Mikkelsen as Will and Hannibal on Hannibal.
7. Zach Braff and Donald Faison as J.D. and Turk on Scrubs.
8. Katherine Barrell and Dominique Provost-Chalkley as Nicole and Waverly on Wynonna Earp.
9. Ellen Pompeo and Patrick Dempsey as Meredith and Derek on Grey's Anatomy.
10. Sarah Drew and Jesse Williams as April and Jackson on Grey's Anatomy.
11. Dan Levy and Noah Reid as David and Patrick on Schitt's Creek.
12. Zooey Deschanel and Jake Johnson as Jess and Nick on New Girl.
13. Christina Applegate and Linda Cardellini as Jen and Judy on Dead to Me.
14. Daisy Edgar-Jones and Paul Mescal as Marianne and Connell on Normal People.
15. Freddy Carter and Amita Suman as Kaz and Inej on Shadow and Bone.
16. Dulé Hill and James Roday Rodriguez as Gus and Shawn on Psych.
17. Kristen Bell and William Jackson Harper as Eleanor and Chidi on The Good Place.
18. Jennifer Morrison and Colin O'Donoghue as Emma and Hook on Once Upon a Time.
19. Melissa Benoist and Katie McGrath as Kara and Lena on Supergirl.
20. Donald Glover and Danny Pudi as Troy and Abed on Community.
21. Amy Poehler and Adam Scott as Leslie and Ben on Parks and Rec.
22. Stephen Amell and Emily Bett Rickards as Oliver and Felicity on Arrow.
23. Indya Moore and Angel Bismark Curiel as Angel and Papi on Pose.
24. Bob Morley and Eliza Taylor as Bellamy and Clarke on The 100.
25. And finally, Jared Padalecki and Jensen Ackles as Sam and Dean on Supernatural.
We can't fit everyone into one post, so which other TV actors who had never met before but have amazing chemistry do you love?
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