74. Elizabeth Hurley, the devil in Bedazzled (2000).
73. Sting, Feyd-Rautha Harkonnen in Dune.
No idea what he’s doing here. Or in most of the movie.
72. Bruce Payne, Charles Rane in Passenger 57.
71. Jonathan Hyde, Van Pelt in Jumanji.
70. Ray Winston, George McHale in Indiana Jones and the Kingdom of the Crystal Skull.
69. Sean Connery, Sir August de Wynter in The Avengers.
67. Cary Elwes, Ella Enchanted and Twister.
To be fair, Cary Elwes may not have made the most effective villain, but he made an EXCELLENT farm boy in The Princess Bride.