This is Anne Hathaway's husband putting his whole mouth/face on her toes:
Ok, now that you've seen the picture I can tell you why this photo exists. The story is that she must have hurt her foot somehow and he is taking care of that foot (by inhaling it).
Luckily for the both of them he seems to carry around an entire bottle of hydrogen peroxide.
And nothing gives him more enjoyment than applying band aids:
